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The nature of the indium electrode potential in acid perchlorate solutions

Identifieur interne : 01A274 ( Main/Repository ); précédent : 01A273; suivant : 01A275

The nature of the indium electrode potential in acid perchlorate solutions

Auteurs : RBID : Pascal:96-0429436

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English descriptors

Abstract

The behavior of the indium electrode in perchlorate solutions in a broad acidity range is analyzed in terms of a model allowing for hydrolysis of the In+ and In3+ ions. The condition of the In+, In3+, and H+ concentration stability is shown to be fulfilled when the reactions of the In3+ ion hydrolysis are taken into account

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Pascal:96-0429436

Le document en format XML

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<title xml:lang="en" level="a">The nature of the indium electrode potential in acid perchlorate solutions</title>
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<name sortKey="Nefedov, A N" uniqKey="Nefedov A">A. N. Nefedov</name>
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<term>Acidic solution</term>
<term>Aqueous solution</term>
<term>Electrode potential</term>
<term>Electrodes</term>
<term>Experimental study</term>
<term>Indium</term>
<term>Modeling</term>
<term>Perchloric acid</term>
<term>Reaction mechanism</term>
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<term>Modélisation</term>
<term>Potentiel électrode</term>
<term>Electrode</term>
<term>Indium</term>
<term>Solution acide</term>
<term>Perchlorique acide</term>
<term>Solution aqueuse</term>
<term>Mécanisme réaction</term>
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<div type="abstract" xml:lang="en">The behavior of the indium electrode in perchlorate solutions in a broad acidity range is analyzed in terms of a model allowing for hydrolysis of the In
<sup>+</sup>
and In
<sup>3+</sup>
ions. The condition of the In
<sup>+</sup>
, In
<sup>3+</sup>
, and H
<sup>+</sup>
concentration stability is shown to be fulfilled when the reactions of the In
<sup>3+</sup>
ion hydrolysis are taken into account</div>
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<s0>The behavior of the indium electrode in perchlorate solutions in a broad acidity range is analyzed in terms of a model allowing for hydrolysis of the In
<sup>+</sup>
and In
<sup>3+</sup>
ions. The condition of the In
<sup>+</sup>
, In
<sup>3+</sup>
, and H
<sup>+</sup>
concentration stability is shown to be fulfilled when the reactions of the In
<sup>3+</sup>
ion hydrolysis are taken into account</s0>
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<s5>06</s5>
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<s5>06</s5>
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<s0>Reaction mechanism</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Mecanismo reacción</s0>
<s5>08</s5>
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<s0>Experimental study</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="GER">
<s0>Experimentelle Untersuchung</s0>
<s5>09</s5>
</fC03>
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<s0>Estudio experimental</s0>
<s5>09</s5>
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<fN21>
<s1>295</s1>
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